What does formaldehyde smell like? Negative effects of formaldehyde on the body and symptoms of poisoning. The main areas of application of medical formalin

The site provides reference information for informational purposes only. Diagnosis and treatment of diseases must be carried out under the supervision of a specialist. All drugs have contraindications. Consultation with a specialist is required!

Formalin is a solution of formaldehyde. Main Applications
technical formalin

Formalin is a 40% aqueous solution of formaldehyde, which contains about 8% (6-15%) methyl (technical) alcohol as a stabilizer. It is a clear, colorless liquid with a very characteristic suffocating odor.

Formaldehyde is used in industry as a source of formaldehyde, as well as for the production of methylene derivatives.

Formaldehyde's ability to coagulate proteins is used to tan gelatin in the production of film, to increase the strength of fabrics and paper, to tan leather, etc.

Formalin has become widespread as a disinfectant: in agriculture for treating seeds and disinfecting soil, in livestock farming for disinfecting premises.

Because formaldehyde prevents decomposition, it is used as an embalming agent for long-term storage of biological specimens.

When storing high-quality formaldehyde, sediment is allowed to form, which dissolves when the temperature rises to 40 degrees. The shelf life is three months from the date of release of the substance.

Technical formalin is contained in corrosion-resistant containers (aluminum or steel containers coated with an anti-corrosion surface, polyethylene bottles, etc.). Storage temperature for formaldehyde: 10-20 degrees above zero.

Use of formaldehyde in medicine

General characteristics of medical formalin

Medical formaldehyde has an international name formaldehyde solution (Solutio formaIdehydi) , while the concentration of the active substance is, as a rule, 36.5 – 37.5%.

Used exclusively for external use, as a disinfectant, deodorizing, cauterizing and astringent.

The main areas of application of medical formalin:

  • hand disinfection (0.5%);
  • washing feet with excessive sweating (0.5 – 1%);
  • disinfection of instruments (0.5%);
  • solutions for douching (dilutions 1:2000 – 1:3000).
Store medical formalin in well-sealed bottles, in places protected from light, at a temperature of 10-20 degrees above zero.

Formalin, as an active ingredient, is included in a number of medications. The most famous of them: formidron, formaldehyde ointment, lysoform, Teymurov's paste.

Formidron

Formidron is a liquid produced in bottles of 50 and 100 ml. This solution contains about ten parts of formaldehyde, forty parts of medical alcohol and fifty parts of water. The liquid is deodorized with a small concentration of cologne (0.5%).

Used for excessive sweating in certain areas of the body. According to the instructions, soak a cotton swab with formidron and wipe areas of excessive sweating with it, no more than once a day.

Contraindications to the use of formidrone are hypersensitivity to formaldehyde and inflammatory skin diseases. The instructions for the drug formidron warn: you should not treat the armpits with the drug immediately after shaving.

Formalin ointment

Formalin ointment is a drug based on formaldehyde, which contains boric and salicylic acid, which also have antiseptic properties. The drug is produced in tubes of 50 and 100 grams, and externally it is a white ointment with a faint odor of formaldehyde and fragrance.

The drug is indicated for use in cases of excessive sweating. A small amount of ointment is rubbed into the armpits and/or interdigital spaces. Formalin ointment can cause irritation, so it is strictly not recommended to lubricate the face and areas with delicate skin.

The instructions for use of formaldehyde ointment warn that this drug should not be used by patients who have an allergy to salicylates or boric acid preparations. Any local inflammatory phenomena, including skin irritation, are also contraindicated for use.

Lysoform

Lysoform is a soap solution of formaldehyde (contains 40 parts of formaldehyde and potassium soap, and 20 parts of ethyl alcohol). Has a pronounced disinfectant and deodorizing effect.

This drug is a clear, yellowish-brown liquid with a noticeable odor of formaldehyde and is miscible with water in all proportions. Available in bottles.

Lysoform is used in gynecological medical practice for douching (1-4% aqueous solutions), as well as for disinfecting hands, working tools and premises (1-3% aqueous solutions).

Pasta Teymurova

Teymurov's paste is a white or slightly grayish substance of semi-liquid consistency, which has a rather complex composition. In addition to formaldehyde solution, the drug contains boric and salicylic acid, zinc oxide and other substances that have an antiseptic, deodorizing, astringent and drying effect.

According to the instructions, Teymurov's paste is used for excessive sweating of the feet. It is recommended to apply a thin layer of paste to the spaces between the fingers no more than twice a day.

Side effects of the drug include allergic reactions and increased sensitivity to the drug, which can manifest as headache and fatigue, and in rare cases, nausea and vomiting. If unwanted effects occur, you should stop using this medicine.

The instructions for the medicinal product Teymurov's paste warn: do not apply the medicinal substance over too large an area.

The effect of formaldehyde on the human body. Precautionary measures. Contraindications
to the use of medical formalin preparations

Many properties of formaldehyde make it possible to consider it as an ideal remedy for excessive sweating. First of all, these are high antiseptic qualities (the unpleasant odor of sweat is largely due to the waste products of microflora). In addition, the ability of formaldehyde molecules to bind ammonia determines the pronounced deodorizing effect of medical formalin. Finally, the drug dries the skin, eliminating unpleasant moisture.

The list of advantages of these medicines is complemented by their availability - you can buy formalin and its preparations in any pharmacy at a fairly low price. Therefore, it is not surprising that, for example, such products as formidron and Teymurov’s paste have received many positive reviews both on the Internet and beyond.

However, it should be remembered that medical formalin, like a solution of formaldehyde, belongs to class IIB toxic substances.

In high concentrations, formalin has an extremely adverse effect on the human body. First of all, it has a detrimental effect on the skin, mucous membranes of the respiratory tract, and when it enters the bloodstream, the central nervous system.

With prolonged topical use, medical formalin can severely dry out the skin and contribute to the occurrence of inflammatory reactions.

Since formaldehyde has the ability to accumulate in the body, in case of improper and uncontrolled use it can exhibit its inherent mutagenic and carcinogenic effects.

Recently, many negative reviews have appeared about Teymurov’s paste and formidron, indicating the possibility of these drugs to cause allergic reactions.

Thus, when using drugs containing medical formaldehyde, the following precautions should be taken:

  • You cannot use medical formaldehyde preparations for application to damaged or inflamed skin (in such cases, the permeability of the skin barrier is increased, and the active substance can penetrate the body in an amount sufficient to have a mutagenic or carcinogenic effect);
  • Long-term uncontrolled use of solutions of medical formaldehyde and its preparations should be avoided, especially with regard to skin treatment (the skin of the legs, being rougher, represents a more reliable barrier);
  • You should not use such medications during pregnancy and breastfeeding;
  • when using medical formalin preparations, you should carefully read the instructions and do not apply the medicine more often than recommended by pharmacologists;
  • It is strictly contraindicated to use these drugs to lubricate the face;
  • in case of accidental contact of medical formaldehyde preparations with the eyes, it is necessary to urgently rinse the conjunctiva with running water;
  • it is best to buy formalin at a pharmacy, giving preference to drugs that have a lower concentration of formaldehyde due to a combination of several active ingredients with similar properties (Teymurov’s paste);
  • when the first signs of undesirable effects appear (allergies, irritation, dry skin), in accordance with the instructions for use of medical formaldehyde solutions, you must stop using the drug and seek help from professionals.

Acute poisoning with formaldehyde (formaldehyde)

Acute formaldehyde poisoning is quite rare. Among the causes, accidents at home and at work, caused by violation of safety rules for working with formaldehyde, prevail.

Acute formaldehyde vapor poisoning can occur if formaldehyde solutions are used incorrectly to disinfect premises.

Even a slight excess of the permissible concentration of formaldehyde in the air of enclosed spaces can cause headaches and lacrimation; in case of poisoning with higher concentrations, nausea, vomiting, and symptoms of irritation of the upper respiratory tract occur.

Severe intoxication with formalin vapor leads to swelling and spasm of the larynx with the development of acute respiratory failure. Death usually occurs from pulmonary edema.

Accidental or intentional ingestion of formaldehyde causes acute pain, nausea, and bloody vomiting. Death occurs as a result of general toxic shock; the lethal dose of formalin when entering through the digestive tract is 50 ml.

When high concentrations of formaldehyde come into contact with exposed areas of the body, multiple burns occur.

When providing primary care, specific antidotes (antidotes) are used to neutralize formaldehyde, which are ammonia and urea preparations (they react with formaldehyde to form harmless methenamine). The affected skin is washed with a 5% solution of ammonia; if formaldehyde gets inside, the stomach is washed through a tube (inducing vomiting is strictly contraindicated) with a solution of ammonium and urea salts. In case of formalin vapor poisoning, inhalation of water vapor with the addition of a few drops of ammonia is indicated.

In the future, measures are taken to help remove formalin from the body - intravenous administration of urea solution and the prescription of diuretics. At the same time, local treatment of burns is carried out. If formaldehyde enters the gastrointestinal tract, egg whites and mucous decoctions are injected into the stomach to neutralize the cauterizing effects of formaldehyde.

With the development of shock and collapse, urgent resuscitation measures are indicated.

Prevention of poisoning at home and at work is strict adherence to all safety rules for working with formaldehyde, thorough ventilation of premises after treating work surfaces and instruments with formaldehyde solutions, storage of formaldehyde and other toxic substances in accordance with the instructions.

Formaldehyde (synonyms: methanal, formic aldehyde, methyl aldehyde; chemical formula CH2O) under normal conditions is a colorless gas with a pungent odor, highly soluble in water. This substance is produced on an industrial scale by oxidizing methanol. In the article, we will discuss in more detail the sources of formaldehyde release, how long it takes for it to disappear, the norms of H2CO content in the air, the effect of formaldehyde on the body, and the symptoms of carcinogen poisoning.

The bactericidal properties of this chemical compound have been known for quite some time - the familiar formaldehyde, used in anatomy for the preservation of tissues and organs, is a common 40% aqueous solution of formicaldehyde. Tanning properties have made it an indispensable component of products for the leather and woodworking industries. In addition, it is used in the production of various cosmetics, as well as in the food industry (as an additive under code E240).

What are the main sources of formaldehyde emissions in an apartment?

First, pairs are free formaldehydeare part of combustion products organic substances:

  • smog, car exhaust
  • tobacco smoke and even smoke from electronic cigarettes
  • evaporation from the fireplace and gas stove

Secondly, formaldehyde evaporation occurs from household materials:

  • Chipboard (from which most furniture is made)
  • plywood, MDF, OSB (used for finishing and insulating the house)
  • laminate and other floor coverings, baseboards, doors and slopes made of MDF

Thus, it can be found everywhere in everyday life. Even such seemingly harmless things as a sofa, bed, table, chairs and floor can serve as sources of formaldehyde release in the air in an apartment (house). It is very important to note that wooden furniture does not contain formaldehyde, but it is much more expensive than those made from MDF and chipboard.

How long does it take for formaldehyde to disappear from chipboard furniture and laminate flooring?

On average, formaldehyde disappears from furniture and floor coverings in about 3 - 5 years.

In the case of upholstered furniture, its release can occur even after 10 years of use.

What are the health risks of formaldehyde and the symptoms of poisoning?

Toxicology scientists have proven that formaldehyde is harmful to human health. However, it should be understood that it is dangerous (toxic) only when ingested. While, upon contact with the skin, it causes only local irritation, which quickly passes. That is why you should not be afraid of this substance, for example, in shampoos - the shampoo is washed off with water and the small amount of aldehyde in it can only cause an allergic reaction in people (and even then, according to statistics, the frequency of such cases is only 1 in 75,000).

Formaldehyde vapor poses a much greater danger. After all, chronic formaldehyde poisoning causes the following symptoms:

  • allergies, persistent cough, irritation of eyes, nose, throat and skin, asthma attacks
  • sleep disturbance, mental agitation, tremors, weight loss
  • headaches, blurred vision and coordination
  • chronic fatigue, drowsiness, lethargy, lethargy
  • disorder of sweating and body temperature regulation

The first signs of acute formaldehyde poisoning: lacrimation, pain in the eyes, runny nose, cough, shortness of breath, suffocation, headache, impaired coordination of movements, convulsions. When inhaling its vapors, allergic skin reactions (including eczema) may occur, and in women the menstrual cycle is disrupted.

As a rule, the consequences of formaldehyde poisoning go away on their own when its source is eliminated and do not require the help of a doctor. But, when inhaled in high concentrations, acute conjunctivitis, rhinitis, bronchitis, edema in the lungs and pharynx develops. Death can occur when the concentration of this gas in the atmosphere is 20 mg/m 3 within 30 minutes.

Can formaldehyde cause cancer?

The fact that formaldehyde is a human carcinogen (a substance that can cause cancer) has not been 100% proven. But, in some animal experiments it has been shown that it increases the risk of developing nasopharyngeal cancer and can also lead to leukemia.

Therefore, it is listed as a potentially carcinogenic compound under "probably carcinogenic to humans."

Anyway the effect of formaldehyde on the human body is extremely negative!

What are the standards for formaldehyde in the air?

We are more interested in the everyday side of the issue - is it possible to harm your health without leaving your apartment and without even knowing it? As it turns out, it is possible if your home constantly has excessive levels of formaldehyde in the air.

The first sign of excess formaldehyde vapor content in the air is a characteristic pungent odor. It may be familiar to you as a special “hospital” or “pharmacy” aroma. Many people associate it with new furniture - but in reality this is what formaldehyde fumes smell like. Its smell is already felt at a concentration 25 times less than permissible according to sanitary standards. By the way, the MAC (maximum permissible concentration) of formaldehyde in the air is 0.5 mg/m³, while the daily MAC is five times less - 0.01 mg/m³.

So, when purchasing new furniture (laminate, plywood products, finishing materials made from OSB, MDF, chipboard, etc.), the presence of odor is quite justified. It’s much worse if it hasn’t disappeared within a few days – now it’s time to think about it! And if at the same time you begin to experience a loss of strength, depression, and your face turns pale, the methanol almost certainly continues to evaporate from the interior items (more precisely, from the resin that glues wood chips together), and you continue to inhale it. Therefore, you need to protect yourself in advance!

Is there any protection against formaldehyde?

  • Firstly, it is advisable to buy products made from solid wood (although in their production, manufacturers often use harmful components), but if this is not possible, then you can ask the seller for documentation or make it yourself. According to this property, furniture is divided into three classes (class E1 - aldehyde content not exceeding 10 mg per 100 g of dry wood board, while class E3 - 60 mg). Accordingly, the cost of products will be different - the less harmful components in the resin, the more expensive it is.
  • Secondly, you should not place objects made of chipboard and MDF near heat sources - near radiators, in direct sunlight, etc.
  • Before bringing furniture, laminate, plywood and other finishing materials into the apartment, let them “air out” outside.
  • In addition, the most common ventilation of the room is useful. Even better, install an air purifier, this will help partially neutralize the formaldehyde in the air.
  • We should also not forget that green plants in the house not only create comfort, but also purify the air.
  • Of course, you should stop smoking indoors, even if you use electronic cigarettes.

How can you do an analysis to determine formaldehyde in the air?

It is difficult to determine formaldehyde on your own; this requires special laboratory equipment and chemical reagents.

Formaldehyde. Properties and Applications

- formic acid aldehyde, the first member of the homologous series of aliphatic aldehydes. The term formaldehyde comes from the Latin. formica - ant, in English. formaldehyde, German Formaldehyd, international name - metanal. Some synonyms - Formic aldehyde, Methaldehyde, Methyl aldehyde, Methylene oxide, Oxomethane, Oxymethylene

An aqueous solution of formaldehyde is called formalin.

The formula of formaldehyde is very simple - CH2=O (or HCHO); Moreover, the formaldehyde molecule differs from the water molecule by the addition of only one carbon atom.

Formaldehyde is a gaseous, colorless substance with high chemical and biological activity, highly soluble in water and alcohols. Formaldehyde easily (sometimes spontaneously) polymerizes to form various solid forms of formaldehyde - (CH2=O)n: trioxane, tetraoxane, polyformaldehyde, paraformaldehyde, polyoxymethylene.

Formaldehyde is widely present in natural processes and can even be found in outer space. Scientists do not exclude its participation in the processes of the origin of life. Formaldehyde is specially produced industrially as a raw material for the production of various chemical products.

Properties of formaldehyde

Under normal conditions, a colorless gas with a pungent, irritating odor.

Molar mass 30.03 g/mol
Density 0.9151 g/cm³ (at −80 °C)
Solubility in water up to 37%
Melting point −92 °C
Boiling point −19.2 °C
Explosion category II B
Explosion group T2
Concentration limits of ignition 7-73% vol.
Auto-ignition temperature 435 °C


Formaldehyde has strong antiseptic properties and is capable of destroying most microorganisms, including their spores. Toxic, negatively affects the respiratory tract, eyes, skin, genetic material, reproductive organs, and has a strong effect on the central nervous system.

The International Agency for Research on Cancer (IARC) under the WHO classifies formaldehyde as a carcinogen.
see report Vol.: 88 (2006) CAS No.: 50-00-0. Formaldehyde causes allergies in some people.

In terms of toxicity, formaldehyde belongs to hazard class 2 (highly hazardous - similar to chlorine, dichloroethane, carbon disulfide, etc.) according to GOST 12.1.005 "General sanitary and hygienic requirements for the air of the working area"

For air in populated areas, the maximum permissible single concentration of formaldehyde is MPCm.r. = 0.035 mg/m³, maximum permissible average daily concentration of MPCs.s. = 0.003 mg/m³ (installed
Hygienic standards GN 2.1.6.1338-03 “Maximum permissible concentrations (MPC) of pollutants in the atmospheric air of populated areas” (approved by the Chief State Sanitary Doctor of the Russian Federation on May 31, 2003)

The maximum permissible concentration of formaldehyde in the air of the working area is MPC = 0.5 (established by Hygienic Standards GN 2.2.5.1827-03 "Maximum Permissible Concentrations (MAC) of Harmful Substances in the Air of the Working Area") The lethal dose of a 35% aqueous solution of formaldehyde (formalin) is 10 - 50 g.

In emergency situations, gas masks of grades A and M are used according to GOST 12.4.121.

Technical forms of formaldehyde cause rapid corrosion of carbon steels and aluminum alloys.

Obtaining formaldehyde

In industry, formaldehyde is produced by the oxidation of methanol (2CH3OH + O2 → 2HCHO + 2H2O) or methane (CH4 + O2 → HCHO + H2O). The processes are carried out at elevated pressure and temperature in the presence of various catalysts.

The bulk of commercial formaldehyde is supplied in the form of formalin - a water-methanol solution (35-37% formaldehyde, 6-11% methanol) or an aqueous solution (37% formaldehyde). In 2005, global formaldehyde production amounted to 21 million tons.

Formaldehyde (formalin) is produced at many domestic chemical plants, for example: Akron (Veliky Novgorod), Karbolit (Orekhovo-Zuevo, Moscow region), Metafrax (Gubakha, Perm region), Uralchimplast (Nizhny Tagil, Sverdlovsk region), Tomskneftekhim (Tomsk) , Novocherkassk Synthetic Products Plant (Rostov region), etc.

Application of formaldehyde

Most of the formaldehyde is used for the production of phenol-formaldehyde, urea-formaldehyde, melamine-formaldehyde, amido-formaldehyde resins used in the production of particle boards and fiberboards, phenol plastics and amino plastics (for example, fiberglass) and other composite materials, adhesives, varnishes, grinding materials, etc.

Formaldehyde is used in the production of isoprene, polyacetal resins, pentaerythritol, trimethylopropane, methenamine, etriol, diphenylmethane isocyanate (MDI) and some other chemicals.

An aqueous solution of formaldehyde - formalin - is used for tanning and preserving biological materials, and also as a disinfectant (antiseptic) in biology, medicine and agriculture.

Formaldehyde is used in the manufacture of antibacterial vaccines; sometimes formaldehyde-based medications (solutions, powders, ointments) are used to treat sweating.

Environmental aspects of formaldehyde

Formaldehyde is one of the normal metabolites in the body associated with the metabolism of derivatives of the tetrahydrofolic acid system. However, it has long attracted the attention of hygienists, toxicologists and allergists from the standpoint of its adverse effects on organisms. The neutralization of formaldehyde in organisms comes down to its oxidation and excretion by the kidneys in a bound and free state.

Formaldehyde can be found in large quantities in the atmosphere, especially in large cities and industrial centers. Sources of formaldehyde in the atmosphere are:

  • photochemical reactions of the transformation of methane (and possibly other hydrocarbons) in atmospheric layers;
  • forest, peat and urban fires; landfills for household and industrial waste;
  • emissions from vehicles and flue gases from power plants;
  • emissions from industrial enterprises that use formaldehyde in their activities;
  • release of formaldehyde from materials containing it (wood panels, phenolic plastics).
A significant decrease in formaldehyde in the atmosphere occurs in winter, as well as after rains.

The absorption of formaldehyde in nature is carried out by methanotrophic bacteria, in particular methylotrophs - widespread inhabitants of various bodies of water (lakes, swamps, rivers and seas) and soils.

In everyday life, formaldehyde can be released from furniture, construction and finishing materials, insulation materials, textile materials, cosmetics and disinfectants. Formaldehyde is found in tobacco smoke, as well as in some types of vegetables, fruits and drinks (natural wines, cognacs, beer).

For example, incompletely reacted formaldehyde may be released from phenoplastics, particle boards and wood fiber boards, as well as formaldehyde resulting from the destruction of phenol-formaldehyde resin, for example, when operating furniture and building structures in a wet state.

Formaldehyde emissions from various materials or products are regulated by relevant international standards, for example:

EN 300:1997, Oriented Strand Boards (OSB) – Definitions, Classification and Specifications
EN 312-1:1997, Particleboards – Specifications – Part 1: General Requirements for all Board Types
EN 622-5:1997, Fiberboards – Specifications – Part 5: Requirements for Dry Process Boards (MDF)
EN 636-1:1996, Plywood – Specifications – Part 1: Requirements for Plywood for Use in Dry Conditions
EN 636-2:1996, Plywood – Specifications – Part 2: Requirements for Plywood for Use in Humid Conditions
EN 636-3:1996, Plywood – Specifications – Part 3: Requirements for Plywood for Use in Exterior Conditions


Different countries also have different national standards regarding formaldehyde content (emissions) and different methods for determining these emissions. In our country, formaldehyde emission standards are established for particle boards GOST 10632-2007 "Particle boards. Technical conditions"

Currently, eliminating the emission of formaldehyde from building materials and furniture can be achieved, for example, by replacing particle boards and fiberboards with thermoplastic wood-polymer composites; for more details, see special

Standards

GOST 1625-89 Technical formalin. General technical conditions

F ormaldehyde online

Numerous literature is devoted to formaldehyde, incl. available online. For a first impression for example:

Books about formaldehyde

Ogorodnikov S.K. Formaldehyde, Leningrad, ed. Chemistry, 1984, 280 pp.

Atmospheric pollution with formaldehyde, Skubnevskaya G.I., Dultseva G.G. , under. ed. N.M. Bazhina. - Novosibirsk, 1994. - 70 p.


Compiled by Abushenko Alexander Viktorovich
July 2009

People constantly come into contact with chemical elements without understanding the danger they pose to health. Formaldehyde is a toxin that accompanies people everywhere. To reduce the negative impact on the body and prevent diseases, it is necessary to study its properties in detail.

What is formaldehyde

Formaldehyde (methanal, formic aldehyde) is a flammable colorless gas that has a strong unpleasant odor. The physical properties of the substance include high toxicity, soluble in both ordinary water and alcohol.

In chemistry, formic aldehyde is designated by the formula CH2O. The aqueous solution is called formalin, it has the ability to denature protein.

Obtaining formaldehyde


Formaldehyde can be obtained in industrial conditions due to the actions of methanol under a certain oxidation environment. A silver catalyst is used at a temperature of 650 degrees. This method produces 80% formaldehyde. The substance with this method of preparation has high solubility and chemical activity.

When using an iron-molybdenum catalyst, the possibility of creating a dangerous compound is 99%.

The degree of reaction heating reaches 300 °C. You can also get formaldehyde by oxidizing methane using aluminum phosphate at 450 degrees. Under laboratory conditions, it is obtained by dehydrogenating methanol over copper, and zinc formate decomposes under the influence of temperatures.

The sources of methanal are divided into natural and man-made. The former include forest fires, plants, animal excretions, swamps, and volcanic eruptions. And the second sources are tobacco smoke, motor vehicles, extraction and transportation of petroleum products, thermal power plants, housing and communal services, and during the combustion of hydrocarbons.

Areas of application


Since poisonous gas has a huge number of properties, it has found use in such areas as the chemical, woodworking, furniture, food industries, tanning, medicine, cosmetology, and agriculture.

The compound is widely used in the manufacture of plastics based on phenol-formaldehyde resins, wood-based products, and the processing of animal skins. Formic aldehyde is contained in adhesives and paints and varnishes. In the food industry it is used as a preservative when smoking products.

Formalin (liquid formaldehyde) is used in formalceuticals, an antiseptic - during treatment for chickenpox, for disinfection of instruments, hands, during embalming and preservation of anatomical parts. Methanal is included in ointments, creams, shampoos, bath bubbles, nail polishes, and detergents.

Using technical formaldehyde, the soil is disinfected.

Maximum permissible concentrations and emissions of formaldehyde


Harmful gas is released into the atmosphere through emissions from industrial enterprises and cars.

Toxic substances are divided into several hazard classes. They are assigned depending on the specific properties of a given compound. Formaldehyde received the second class of danger due to its toxicity; it is a poison for humans.

The maximum permissible concentration in the air of a populated area for formaldehyde is 0.035 mg/m3, the permissible concentration in a work area is 0.5 mg/m3, soil is 7 mg/kg, water is 0.05 mg/l.

The level of danger of a particular item depends on the degree of emission (emission) of formic aldehyde. It is possible to reduce the poison content by lowering the temperature, relative humidity and ventilation rates. It is impossible to completely stop the release of the substance.

Effects of formaldehyde on human health


Poisonous gas causes great harm to the body. It has a negative effect on the liver, kidneys, eyes, disrupts the nervous and immune systems, and the child may develop asthma. If poison enters the bloodstream, the process of removing it from the body becomes very difficult.

There is a risk of poisoning by inhaling vapors if an employee violates safety precautions at industrial enterprises where methanal is used, drinking an aqueous solution by mistake or trying to poison himself if it comes into contact with the skin through negligence.

When intoxicated by vapors, formaldehyde has a particularly negative effect on the human body.

During prolonged inhalation, liver and kidney failure occurs, skin and mucous membrane allergies appear, the functioning of the respiratory and nervous systems is disrupted, and cancer occurs.

The main symptoms of poisoning are drowsiness, migraine, lethargy, weakness, lethargy; a chronic cough may also appear, vision decreases, and shortness of breath begins. The person becomes mentally unbalanced and depressed.

There is no difference between the symptoms of intoxication in children and adults.

Initial signs of vapor poisoning: nausea, vomiting, diarrhea, persistent cough, choking, runny nose, convulsions, in women the menstrual cycle is disrupted, cervical disease. When interacting with the skin, itching, redness, and dermatitis are observed.

A large accumulation of a toxic substance and prolonged inhalation of the poison causes pulmonary edema and, as a result, death of a person. During pregnancy, intoxication in a woman can lead to miscarriage.

Since formaldehyde is a carcinogen, it affects the proliferation of cancer cells. People who work in laboratories, producing methanol, in woodworking enterprises, and furniture factories are most susceptible to cancer. Most often, cancer develops in the lungs, upper respiratory tract, and stomach.

Treatment of formaldehyde poisoning


In case of formaldehyde intoxication, the victim must provide first aid by performing the following therapeutic actions:

  1. Ventilate the room or take it out into fresh air.
  2. Provide the patient with plenty of water or warm tea.
  3. Call an ambulance.
  4. If the substance gets on the skin, rinse the affected area under running water for 20 minutes.
  5. Having lost consciousness, place the person on his back, turn his head to the side, and check his breathing.
  6. As an antidote, give the poisoned person a whiff of cotton wool soaked in ammonia.
  7. It is forbidden to provoke vomiting on your own, since vomit containing poison can re-burn the internal digestive organs.

Upon arrival, ambulance doctors perform certain therapeutic actions and symptomatic treatment, and determine the characteristics of the patient’s condition. The victim is given a drug that reduces the effects of toxins. They drink protein-rich liquids, treat burns, wash out the stomach, and do an enema.

If necessary, anti-shock therapy is carried out and pain is treated with special means. A person's blood and urine are tested and he undergoes an ultrasound examination of all organs. If internal bleeding occurs, the patient is urgently operated on.

An enema and gastric lavage are done to accelerate the removal of ketone bodies (acetone, acetaldehyde) from the intestines.

In case of poisoning, you should follow the necessary diet, giving preference to dairy products, prepare porridge without oil, chopped vegetable puree, chicken broth (on chicken breast), hot drinks (strong tea, rosehip infusion).

It is prohibited to eat smoked products, pickle and ferment, fried foods, drink coffee drinks, cocoa, alcohol, and stop smoking.

Intoxication of the body with formaldehyde vapor and its solution leads to blindness, infertility, chronic liver and kidney diseases, oncology and even death.

The mineral tourmaline has received wide recognition in folk medicine for certain symptoms. However, poisoning cannot be treated at home. If the patient contacts doctors in a timely manner, the likelihood of damage to health, as well as severe consequences or death, is significantly reduced.

Prevention of formaldehyde poisoning


Unlike other harmful elements, it is completely impossible to avoid contact with formaldehyde; it surrounds us everywhere. There is a possibility of reducing its level. It is worth following the rules listed below.

In the room it is necessary to control the humidity and temperature of the air; when these indicators increase, the concentration of harmful substances increases, it is necessary to ensure good ventilation and regular airing.

It is harmful to smoke indoors.

Houseplants absorb hazardous emissions well (chlorophytum, ficus benjamina, indoor ivy), which helps reduce the content of pollutants.

If possible, purchase only high-quality furniture. Having bought something made of synthetic fabric, you should definitely wash it. Soak salted fish before eating. When choosing fresh meat, it should not have a pungent chemical smell.

Try to avoid places with high concentrations of emissions (industrial areas, traffic jams, furniture factories).

If you come into contact with formaldehyde at work, use personal protective equipment (respirators, masks, goggles, overalls), and wash your hands more often. Get checked regularly.

By following these measures, the likelihood of poisoning by toxins is minimized.

Formaldehyde is a colorless gas with a rather pungent odor. This substance is present in many manufacturing processes, putting workers in such industries at risk of exposure to formaldehyde. But people can feel the toxic effect of this substance even in everyday life, because formaldehyde surrounds us everywhere.

Where does formaldehyde come from?

Formaldehyde is formed as a result of the vital activity of animals, some plants, and is a by-product of forest fires and volcanic gases. Thus, formaldehyde is constantly in the air in a certain concentration. But human activity can significantly increase this concentration. Formaldehyde is released into the atmosphere with exhaust gases from vehicles, as well as as a result of the activities of wood processing enterprises, oil production and transportation, furniture production, leather goods, etc.

Aqueous solution of formaldehyde - formalin - used in the cosmetic, pharmaceutical, paint and varnish industries. Formalin is known for its antiseptic properties and is therefore used in the production of medicines, for example, Teymurov's paste. It is also known that clothes called “second-hand” are also treated with formalin-containing products, which is why they acquire a specific smell. Formaldehyde is used as a preservative, which helps extend the shelf life of the product. Hairdressers also expose themselves to formaldehyde, because this component is included in the composition used in keratin hair straightening.

Formaldehyde is also found in wood boards, plywood, parquet and linoleum. This means that even your own home can be a source of toxic substances. The danger is that the evaporation of formaldehyde from the material and, accordingly, an increase in its concentration in the air is observed with increasing temperature. But do not panic; reputable manufacturers of materials are required to conduct tests of their own products for the content of toxic substances, in particular formaldehyde. This is the case when, when choosing parquet or wood boards, it is better to overpay than to save money and not know about the content of hazardous substances in them.

Toxic effects of formaldehyde

According to sanitary standards, the use of up to 0.1% formaldehyde in oral hygiene products and up to 0.2% in other cosmetics is allowed. In pharmacy, drugs containing this substance in a concentration of less than 0.5% can be used without restrictions, and only drugs containing formaldehyde in a concentration of more than 5% are not recommended for use on the face. The use of formaldehyde in aerosols and sprays is prohibited.

The effect of formaldehyde was studied on experimental animals. The rabbit's ear was placed in formaldehyde (37% formaldehyde solution) for half an hour, after which redness and peeling of the skin were observed. However, after some time, the skin was completely restored.

Formaldehyde is often used in cosmetics that do not require prolonged exposure to the skin. Basically, the substance is added in a concentration of less than 0.1% as a preservative in shampoos and bath foam. The results of a study using shampoo with a 0.1% concentration of formaldehyde indicate that an adverse skin reaction occurred in one person in 75 thousand people. However, it is not known for certain which component of the shampoo could provoke such a reaction.

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To summarize, we can say that formaldehyde poisoning when using cosmetics containing this preservative is unlikely, because its concentration is negligible and is not capable of causing the development of a pathological condition.

However, formaldehyde is still not so harmless. This substance is probably carcinogenic to humans. Moreover, its carcinogenicity for animals has been reliably proven. There is evidence that formaldehyde, used as an antiseptic and preservative, is associated with an increased risk of nasopharyngeal cancer.

Symptoms of poisoning

Formaldehyde is a toxic substance that irritates the respiratory tract, skin, eyes, and central nervous system. The lethal dose of formaldehyde (40% formaldehyde solution) is only 10-50 grams. The lethal dose of pure formaldehyde is 10-90 ml. The formaldehyde content in the air is lethal for laboratory rats - 578 mg/m³ for four hours.

People who work in industries that use or produce formaldehyde are most susceptible to poisoning. The maximum permissible concentration (MPC) of formaldehyde in the air of the working area is 0.5 mg/m³.

Symptoms of chronic formaldehyde poisoning are:

  • Weakness;
  • Fast;
  • Weight loss;
  • Depressed mood/euphoria;
  • Labored breathing;
  • Seizures;
  • Night;
  • Paleness of the skin.

Acute inhalation poisoning with formaldehyde is indicated by difficulty breathing and possible development. As toxic fumes are inhaled, the central nervous system is affected: anxiety, a feeling of fear, incoordination, and convulsions appear.

In case of formaldehyde poisoning through the mouth, the victim experiences pain, burning in the throat, along the esophagus, in the stomach, and blood. Such serious complications as laryngeal edema, respiratory arrest, hemorrhagic nephritis, and anuria are also possible.

In workers who come into contact with formaldehyde and its vapors, the hands, faces,... Development is also possible. Gradually, sensitivity to formaldehyde increases.

Urgent Care

In case of acute poisoning with formaldehyde vapor, a person must be taken outside and allowed to breathe by inhalation with water and adding a couple of drops of ammonia - this substance eliminates excess formaldehyde by forming urotropine. In case of laryngeal edema, tracheal intubation or tracheostomy is performed.

If formaldehyde and its derivatives come into contact with the eyes, rinse them thoroughly with water, then drip a couple of drops of a 0.5% novocaine solution with the addition of eight to ten drops of adrenaline (1:1000) per 10 ml of solution.

If the poisoning is caused by ingestion of formaldehyde through the mouth, the victim is given atropine (1 ml of a 0.1% solution subcutaneously), promedol (1 ml of a 2% solution subcutaneously) and aminazine (1 ml of a 2.5% solution intramuscularly). The stomach should be rinsed abundantly with a 2-3% solution of ammonium carbonate, acetate or chloride through a probe (these substances bind formaldehyde in the form of methenamine). The victim is recommended to drink plenty of fluids, as well as a 2% solution of ammonium salts with 10-20% urea, ammonia-anise drops inside. To prevent hepatic-renal failure, a glucose-novocaine mixture is prescribed.

If formaldehyde gets on your skin, you should immediately rinse the affected surface thoroughly with water and then with a 5% ammonia solution.

Depending on the clinical picture of poisoning, the victim may be prescribed oxygen inhalation, cardiac medications for impaired cardiovascular activity, and respiratory stimulants (cytiton, lobe6line) for respiratory impairment or mental agitation.

How to minimize the impact of formaldehyde?

Formaldehyde surrounds us everywhere, at work, on the street, and at home. It is impossible to completely eliminate it, but it is possible to reduce the concentration. What do you need to do for this?

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